technology of coating, resins, pigments and inks industries (hand book)

TECHNOLOGY OF COATINGS, RESINS, PIGMENTS & INKS INDUSTRIES

INTRODUCTION

• Resins
• Architectural paints
• Powder coatings
• Automotive coatings
• Feng Shul
• Creating homes
• Resins
• Monomer modifications
• Changes in vegetable oil and fatty acid component

SIMPLE AND QUICK METHOD FOR THE MOLECULAR WEIGHT DISTRIBUTION STUDIES OF ALL ACRYLICS AND STYRENEACRYLIC EMULSION POLYMERS

• Outcome of approach
• Styrene acrylic emulsion
• Significant observations
• Allacrylic emulsion

EFFECT OF MODIFICATION WITH CARDANOL FORMALDEHYDE RESIN ON THE QUALITY OF RUBBER SEED OIL AND ITS ALKYDS AS BINDERS IN SURFACE COATINGS
 

• Physico chemical Properties of rubber seed oil
• Physico chemical properties  of  commercial CNSL
• Experimental procedure
• Major Fatty acid components of RSO
• Preparation of the alkyds Preparation of cardanolformaldehyde (CF) resins (resoles)
• Modification of RSO and its alkyds with CF resins
• Physico chemical properties of the alkyds
• Properties of the finished alkyds
• Chemical Resistance of the unmodified alkyds

OPTICAL AND RHEOLOGICAL PROPERTIES OF LITHOGRAPHIC INKS

• Crystallinity of Yellow 13-type pigments
• Experiment
• Optical properties of the inks
• Rheology of inks
• Complex viscosity N* and low shear flow
• Comparison of TRM with beadmill + TRM inks 

COATING AND COATING SYSTEM

• Grain storage silos
• Energy saving paints
• Environmental assessment, preparation and protection using ISO standards

PROCESS CYCLE TIME REDUCTION OF HIGH SOLIDS ALKYD USING  TAGUCHI STATISTICAL TECHNIQUE

• Taguchi Statistical Technique (TST)
• Formulation used for 8 experiments as per L-8 Model
• Properties of Resins
• ANOVA summary on MG time
• ANOVA summary on esterification time
• ANOVA summary on colour
• ANOVA summary on drying
• Inference

PEARL LUSTRE PIGMENTS

• Manufacturing and properties of pearl lustre pigments
• Natural pearl Lustre pigments
• Basic lead carbonate
• Bismuth oxychloride
• Metal oxide mica pigments
• Manufacturing process for titanium dioxide mica pigments
• Iron lil oxide mica pigments
• Combination pigments
• New pearl lustre pigments based on silica and alumina flakes
• Effect pigments based on silica flakes
• Effect pigments based on aluminal flakes
• Functional metal oxide mica pigments
• Bright conductive pigments
• Magnetic pigments

DIGITAL TECHNOLOGIES SUPPORT QUICKER, CONSISTENT AND EFFICIENT PRODUCTION OF INK

• Indirect impacts
• Focus on productivity
• Direct delivery

MOLECULAR MODELLING A TOOL FOR POLYMER SYNTHESIS IN COATING INDUSTRY

• Structure property relationship of polyester weatherability using FMOC
• Frontier Densities of MPD and ND esters
• Effect of enzyme and alkaline catalyst on conformation of alkyd
• Kinetic modeling for condensation polymerisation
• Modelling of molecular weight distribution for amino resin
• Compositional heterogeneity in free radical polymerisation
• Statistical or instantaneous heterogenerity
• Multistate heterogeneity
• Perturbed model and process heterogeneity
• Perturbed model and process heterogeneity

COATING PROPERTIES OF CHEMOENZYMATICALLY SYNTHESISED AND CONVENTIONAL ALKYD RESINS

• Experimental
• Materials and methods
• Enzymatic inter esterification oil and linseed oil (Scheme-1)
• synthesis of alkyd resin based on Inter esterification product
• Synthesis of conventional alkyd resin
• Characterization
• Thin layer chromatography
• IR spectroscopy
• Coating properties
• Results and Discussion
• Enzyme catalysed interesterification
• Coating properties of alkyd resins

OLEOCHEMICALS FOR COATING INDUSTRIES

• Process for Oleochemicals Production
• Fat spliting
• Alcoholysis
• Esterification
• Oxidation
• Epoxidation and hydroxylation
• Amidation
• Dimerisation
• Ethoxylation
• Alkyds from oleochemicals
• Isomerisation
• Modification of phospholipids
• Genetic engineering

NOVELTY FINISHES BASED ON ACID FUNCTIONAL ACRYLIC COPOLYMERS

• Hexamethoxymethyldmelamine
• Preparation of Novelty Finishes
• Preparation of hammertone finishes
• Preparation of multicolour finishes (paints)
• Preparation of stipple finishes (paints)
• Application of novelty finishes (paints)
• Characterization of the novelty finishes (paints)
• Results and Discussion
• Nature of resin used in finishes
• Type of pattern
• Viscosity
• Colour
• Gloss
• Films and their evaluation
• Package Stability (Shelf Life) of the Finishes

POLYURETHANE COATINGS

• One back moisture cured urethane systems
• Two pack polyester polyol/polyisocynate system
• Experimental
• Material selection
• Processing and testing

POWDER COATINGS

• Research overview of UV curable powder coatings
• Monitoring the photocuring process
• Prospects for acrylic powder coatings
• Blox thermoplastic powder coatings 

LIQUID CRYSTALLINE POLYMERS FOR SURFACE COATINGS

• Classification of liquid crystalline polymers
• Transition to mesophase
• Position of the mesogenic moiety in the polymer molecule
• Synthesis of liquid crystalline of polymers
• Liquid crystalline acrylic polymers
• Liquid crystalline alkyd polymers, polyester polymers and oligoester diols
• Liquid crystalline epoxy polymers
• Characterization of liquid crystalline polymer
• Advantages of liquid crystalline polymers
• Guidelines for designing of liquid crystalline polymers

SYNTHETIC ORGANIC PIGMENTS

EQUIPMENT USED IN INKS INDUSTRY

• Inventory management system
• Innovative horizontal mill
• Basic functionality
• Top entry mills
• Super fine grinding
• Camberless rolls
• Particle analyzer system

ANTIFOULING COATINGS

• Fouling
• Leaching rate factor
• Dry film thickness
• Antifouling coating types
• Biocidal coatings
• Environmental impact of TBT SPC antifoulings
• Hslf life of TBT compounds
• Replacement for TBT SPC coating
• Nonbiocidal coatings
• Silicone coatings

USAGE OF VEGETABLE OILS IN GREEN INKS

• Fatty acid esters
• Application of fatty esters in inks
• Fatty acid esters as industrial cleaners

POLYMER MODIFIED WATERPROOFING SYSTEM

• Types of available Waterproofing Systems
• Waterproofing as a part of a large coating system

ACCELERATED TESTS FOR ANTICORROSIVE COATINGS

• Coating material properties
• Anticorrosive performance tests
• Atmospheric anti corrosive test
• Immersion/accelerated anticorrosion tests
• Neutral salt spray test
• Cold salt spray
• Continuous condensation
• Simulation of sunlight
• Fluorescent UV lamps
• Cycle corrosion tests
• Types of cyclic corrosion tests
• NACE TMO 184 cyclic corrosion test
• Norsok cyclic test
• Immersion performance tests
• Chemical immersion tests
• Cathodic protection tests
• Sacrificial (Galvanic) CP system ASTM G8(1/5 volts)
• Impressed current cathodic protection system
• Evaluation of coatings

OPAQUE POLYMERS IN LATEX PAINTS

• Principle of opacity
• Particle size
• Opacity of emulsion paints
• Crowding effect
• Opaque polymer in latex or emulsion paints
• Air voids
• Theory of air viids
• Application of Opaque polymer
• Substitution of catcined clay (Al-silicate) with opaque polymer
• Physical Properties of Opaque Polymers
• Benefits of opaque polymer

UV CURABLE POWDER COATINGS

• Curing of powder coatings by using UV light
• Radiation curing
• Basic difference between thermosetting and UV curable powder coatings
• Conventional thermosetting powder coatings
• UV curable powder coatings
• Photoinitiators
• Pigments
• Light stabilisers
• UV absorbers (e.g. solid hydroxy phenyl-s-triazine)
• Processing and application of UV curable powder coatings
• UV sources
• Standard mercury vapour lamps
• Lamps doped with gallium lodide
• Lamps dropped with iron iodide
• UV curing superior quarts laboratory system
• Conveyor belt
• Conveyor belt speed
• UV curing system forR & D unit
• UV powder printer surfacer
• Important properties
• Advantages of UV curable powder coatings over conventional liquid UV curable coatings
• Advantages of UV curable powder coatings
• Limitations of UV curable powder coatings
• Market scenario
• Appeal to the users

POLYURETHANE COATINGS

• Materials
• Preparation of hydroxylated polyesters
• Characterisation
• Determination of molecular  weight, glass transition temperature and viscosity
• Molecular weight and Tg
• Diol variation and viscosity
• Effect of  b-ketoester on the viscosity
• Effect of temperature
• Formulation and performance evaluation of coatings
• Coating formulation
• Preparation of test specimen
• Test procedures
• Percent solids of coatings
• Adhesion
• Tensile properties
• Correlation between adhesion and tensile strength
• Dynamic mechanical properties
• Storage modulus. E
• Determination of crosslink density M and T from DMTA measurements
• Routine or conventional performance evaluation of  coatings
• Corrosion resistance properties
• Correlating the tensile properties dynamic properties and routine test methods

SUPERIOR COATINGS FROM CYCLOHEX ANONE FORMALDEHYDE-CNSL EPOXY BLENDS

• Materials
• Synthesis
• Tests carried our for the study of coating properties
• Dry time
• Hardness
• Gloss
• Adhesion and flexibility
• Storage stability
• Chemical resistance

LUMINESENT BENZANTHRONE COLOURANTS

• 3-Alkoxybenzanthrones
• 3-Alkoxybenzanthrones
• 3-Thiolkoxy and thioryloxy benzanthrones
• 3-Aminobenzanthrone derivatives
• 3-Triazinylaminobenzanthrones
• Benzanthrone azomethine derivatives
• 14-H(2.1.9 mna)   thioxanthene-14-ones

CARBON BLACKS IN CONVENTIONAL AND WATERSOLUBLE PAINT SYSTEMS

• Colouristics
• Influence of the carbon blacks on the colouristics of the coating
• Tests in an alkyd-melamine system
• Typical formulation based on alkyd/melamine system and Test Procedure
• Influence of the carbon blacks on the coloristics based on a water based coating system
• Formulation and test procedure
• Tests in a water based coating containing additives
• Formulation and test procedure Milibase
• Incluence of the carbon black concentration on the jetness
• Aniline black
• Advantages

EPOXY FLOORING COMPOUNDS

• Cementitious surfaces
• Epoxy resins and their mechanisms
• Range of Products
• Chemical classification
• Cross linking mechanism
• Cross-linking with amines
• Products for formulating epoxy floorings
• Conventionally used epoxy flooring resins
• Hardeners
• Epoxy resin flooring compounds
• Trowelled floorings
• Preparation of trowelling mix
• Special effects floorings

DEVELOPMENT OF INTERPENETRATING NETWORK OF URETHANE/ACRYLIC EMULSION FOR HIGH PERFORMANCE COATINGS

• Polyurethane dispersions
• Experimentation
• Preparation of plain acrylic  emulsion
• Preparation of IPN of urethane/acrylic  emulsion polymers
• Preparation of physical blend of PUD and acrylic emulsion polymrs
• Preparation of Paint
• Paint testing
• Initiator selection for development of IPN of urethane/acrylic emulsions
• Influence of urethane/acrylic IPNs on development of hardness as a function of time
• Particle size distribution of emulsions
• % water absorption of emulsion films

USING MELAMINE CROSSLINKERS IN DEVELOPING HIGH PERFORMANCE COATINGS

• Amino synthetics
• Crosslinker reactions

UV CURABLE COATINGS

• Raw materials
• Prepolymers or oligomers
• Types of oligomers
• Vinyl based oligomers
• Acrylic prepolymers
• Acrylated epoxies
• Urethane acrylates
• Polyester acrylates
• Silicone arcylates
• Acrylated acrylics
• Water reducible prepolymers and emulsions
• Advantages of using water based systems
• Disadvantages of using  water based system
• Non-vinyl based oligomers Unsafurated polyester
• Thiol/ene system
• Stability of prepolymers
• Monomers (or) reactive diluents
• Factors the formulators should take care while selecting the monomers
• Difference between monofunctional and multifunctional monomers
• Mono functional monomers
• Multifunctional acrylate
• Pigments/Fillers
• Additives
• Photoinitiators
• Reaction mechanism
• Echanism of polymerization of acrylate prepolymers
• Sources of UV radiation
• Arc Light
• Reflector designs
• Laser light
• Application techniques of UV coatings
• Roll coater
• Curtain coater
• Spray coater
• Applications, advantages and disadvantages of UV curing coatings
• Applications
• Advantages
• Disadvantages
• Advances in UV curable coatings and  futire scp[e
• Powder coatings
• Election beam rcuring

PERYLENE PIGMENTS

• Synthesis and recent developments
• Properties and applications
• Properties and aplications

ADVANCES IN MI NIMIZING DIRT PICK UP ON  EXTERIOR LATEX PAINTS

• Dirt  pick up on latex paints cause and mechanism
• Forms of dirt pick-up
• Chemical nature of dirt
• Quantitative assessment of dirt pick up on  latex paint firm
• Mechanism of dirt release
• Factors promoting dirt release
• Incluence of glass transition temperature
• Influence of monomer type
• Influence of surface cross linking
• Influence of PVC
• Influence of hydrophobicity
• Influence of surface morphology
• Influence of coalescing agents
• Influence of opaque polymer
• Additional methods suggested to minimize the effect of dirt pick up

ENERGY CONSERVATION AND RELATED PAINTS

• Need for energy conservation
• Use of paints in energy conservation
• Paints for solar collectors
• Semiconductor pigmented selective paints
• Inorganic metal oxide
• Pigmented selective paints
• Organic black pigmented selective paints
• Metal dust pigmented selective paints
• Paints for nuclear industry
• Requirements and standards
• Radiations effect
• Radiation resistance of coatings
• Radioactive contamination
• Decontamination of painted surfaces
• Formulation of decontaminated paints
• Types of paints
• Chlorinated rubber based paint
• Epoxide resin paints
• Polyurethane paint
• Paints for radar application
• Types of radar absorbing paints
• Paints for insulation
• Types of insulating paints
• Insulation by paint with hollow microspheres
• Insulation by paint with solid sphere
• Insulation by paint with staple fibres
• Insulation by paint with multi layer coating

RADIATION CURING AND FILM PROPERTIES OF MODIFIED EPOXY RESINS

• Types of epoxy resins
• Bisphenol A based epoxy resin
• Other glycidyl based epoxy resins
• Glycidyl ethers of aliphatic diols
• Aromatic glycidyl amines
• Epoxydised cycloaliphatic olefins
• Gylcidyl esters
• Novolac resins
• Ingredients of novolac
• Formaldehyde
• Acid catalyst
• Radiation curing
• Oligomers (resin or binder)
• Photoinitiators
• Advantages of UV-curing
• Application of UV-curing

PIGMENTS DISPERSIONS

• Experimental Resin preparation
• Performance in an ink application
• Viscosity stability
• Colour development
• Theoretical considerations Physical chemistry characterization
• Colloid properties of pigment dispersions
• Colloid microstructure of pigment dispersions 

COLOUR OF PIGMENTS

• Absorption of visible radiation
• Reflection and refraction light

CAPROLACTONE MODIFICATION OF POLYESTER RESINS

• Unmodified polyester (UP)
• Modified polyester 1(MP1)
• Modified polyester 2(MP2)
• Modified polyester 3(MP3)
• Characterization of the polyester resins
• Crosslinking and characterization of coating films

UTILISATION OF COST EFFECTIVE, NON-TRADITIONAL MATERIALS IN FORMULATION OF PROTECTIVE COATINGS

• Characterization of fly ash and mahua oil
• Isolation of fatty acids from mahua oil
• Formulation of mahua fatty acids (MFA)
• Preparation of resins and their modification
• Characterization of the resins
• Fly ash coatings based on MFA epoxy resins
• Characterization of the coatings
• Properties of fly ash
• Characterization of MFA based epoxy ester resin

FLAME RETARDANT SMOKE SUPPRESSANT COATINGS FOR PVC SHEATHED ELECTRICAL CABLES

• Preparation of FRSS coatings
• Preparation of PVC specimens
• Performance evaluation
• Flammability
• Smoke generation
• Char formation

ALKYD AMINO COMBINATIONS BASED ON NEEM OIL AS FILM FORMING MATERIAL

• Aim of present investigation
• Use of oils in surface coatings
• Neem oil
• Composition of neem oil
• Alkyd resins
• Amino resins
• Analysis of neem oil
• Preparation of alkyd resin
• Preparation of amino resin
• Preparation of mixed resins
• Testing of performances of resin samples 

ACRYLICS

• Terminology and monomers
• Preparation of acrylic resins
• Solution acrylic resins
• Initiation
• Propagation
• Termination
• Solution polymerization technique
• Bulk polymerization
• Suspension polymerization
• Graft copolymerization
• Radiation induced polymerization
• Ionic polymerization
• General properties imparted by acrylics & methacrylic monomers
• Non aqueous dispersion acrylics
• Thermosetting acrylic resins
• Film formation
• Acrylic latexes
• Emulsion polymerization
• Film formation of acrylic emulsions
• Water phase
• Solvent additions
• Effect on film formation
• Glass transition temperature and monomer composition

ADDITIVES IN PAINTS

• Driers
• Paint drier
• Mechanism of drying
• Effect of acidic radicles
• Efficiency of drier
• Manufacture of driers
• Fusion process
• Precipitated driers
• Use of driers
• Properties of various metals
• Cobalt
• Manganese
• Lead
• Cerium
• Zirconium
• Zinc
• Aluminium naphthanates
• Iron
• Calcium
• Copper naphthanate
• Vanadium
• Nickel
• Chromium
• Mercury naphthanate
• Barium
• Cadmium
• Tin soaps
• Magnesium
• Antimony, silver, gold and palladium
• Water borne drier
• General recommendation of driers
• Fish oils
• CNSL-Based Compositions
• Baking type finishes
• Solvent type
• Hydroquinone Phenolic
• Oximes
• Cyclohexanone oxime
• Dispersing and wetting agents
• Anti settling agents
• Thixotropic agents
• Flow and levelling control agents
• Anti foaming agents

POLYESTER BASED WATER BORNE AND SOLVENT BORNE COIL COATINGS

• Solvent Borne Coil Coating Resin
• Water Borne Coil Coating Resin
• Coating BAL-389
• New Glycol Formulations

PROTECTION OF CONCRETE SUBSTRATES USING PROTECTIVE COATINGS

• Differences Between concrete and Metallic Substrates
• Construction Influence
• Coatings used on Concrete
• Organic coatings-Thin film
• Modified epoxies
• Furans
• Organic coatings-Thick film
• Elastomeric coatings
• Resin-Rich system
• Inorganic coatings
• New Versus aged or Deteriorated Substrates
• Quality Assurance 

ZINC DUST PIGMENT

• Scope and Field of Application
• Required Characteristics and Their Tolerances
• Residue on Sieve and Particle size (Optional)
• Sampling
• Determination of Total Zinc Content
• Determination of Metallic Zinc by the Gas Evolution Method
• Determination of Metallic Zinc by the Oxidimetric Method
• Determination of Lead and Cadmium
• Determination of Iron
• Determination of Arsenic
• Determination of Matter Insoluble in Acid

WATER BORNE COATINGS AND THEIR COLOURATION

• Classifications and compositions
• Colourants
• Colouristic properties
• Fastness properties
• Resistance properties
• Specific conductivity
• Resin vehicles
• Additives
• Properties of water borne coatings
• In package
• In application
• In dry film
• Film resistance properties
• Special advantage for printing sector
• Advantages in the paint sector

CYCLOHEXANONE-BASED KETONIC RESINS SUITABLE FOR INK APPLICATION

• Scope
• Technological aspects
• Preparation of ketonic resins from acetone
• From methyl ethyl ketone
• By vinyl polymerisation
• From cyclic ketone
• Thermoplastic resins
• Versatile cyclohexanoneformaldehyde resin
• From acetophenone
• Criteria for selection of a resin for printing inks
• Experimental work
• Experimental procedure
• Applications of ketonic resins

ADHESION OF UV CURABLE INKS AND VARNISHES

ALKYD MANUFACTURING PROCESS USING DESIGNED EXPERIMENTS

• Problem
• Study carried out
• Analysis 

CALCIUM CARBONATE EXTENDERS FOR POWDER COATING SYSTEMS

• Preparation and application
• Test procedures

PIGMENTS FOR PAINTS, INKS AND PLASTICS

DEVELOPMENTS IN RESINS FOR POWDER COATINGS

• Pipes and rebars
• Melting and curing scale
• Role of particle shape and size
• Film thickness

DESIGN OF PAINT FORMULATIONS ON THE BASIS OF SOLUBILITY PARAMETERS OF RESINS, PIGMENTS AND SOLVENTS

• Scratch hardness
• Practical adhesion of coatings
• Water absorption in free films of paint coatings
• Water vapour permeation through free films of paint coatings
• Comparative assessment of the influence of solvent blends

POLYESTER RESIN-A SURFACE COATING AGENT

• Raw Materials
• Curing of Polyester Resin

SUPPLIERS OF PLANT AND MACHINERIES

SUPPLIERS OF RAW MATERIALS

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