plastic additives technology hand book

Chapter 1
Introduction

• Scope
• Definitions
• Additives
• Plastics
• Chemical structure of
• Different Types of
• Plastic Additives
• Accelerators
• Accelerator BBTS
• Accelerator MBT, MBT/MG
• Akroform ETU-22 PM
• Accelerator CBTS NEW
• Activator OT Urea
• Cure-Rite® IBT
• Accelerator EZ & EZ-SP
• Antifoams
• SF100
• Antidegradants
• Akrochem Antiox 12
• Ethanox® 314
• Santoflex® IPPD
• Santoflex® 77PD
• Santoflex® 6PPD
• Antioxidants
• Alkanox® P27
• Antioxidant 60
• BLS® 234 NEW
• Alkanox® TNPP
• Antioxidant S
• BLS® 292 NEW
• Alox® PP18 NEW
• 2-(2H-Benzotriazol-2-yl)-4,6-
• bis(1-methyl-1-
• phenylethyl)phenol NEW 11
• BLS® 1622 NEW
• BLS® 1944 NEW
• 2-tert-Butyl-6-(5-chloro-2Hbenzotriazol-
• 2-yl)-4-
• methylphenol NEW
• Cyanox® 1790
• BNX 1077 NEW
• 4,4'-Butylidenebis(6-tert-butylmcresol)
• NEW
• Cyanox® 2246
• BNX 1225TPR NEW
• Cyanox® 1212
• Cyanox® 425
• Cyanox® LTDP
• Diethyl 3,5-Di-tert-butyl-4-
• hydroxybenzylphosphonate
• NEW
• 1,3-Diphenyl-2-thiourea
• NEW
• Cyanox® STDP
• N,N’-Diethylthiourea NEW
• Distyryl biphenyl NEW
• Dibenzylhydroxylamine
• NEW
• O,O’-Dioctadecylpentaerythritol
• distearyl
• bis(phosphile) NEW
• 1,3-Di-o-tolylguanidine NEW
• 3,9-Bis(2,4-dicumylphenoxy)-
• 2,4,8,10-tetraoxa-3,9-
• diphosphaspiro[5,5]
• undecane NEW
• Dipentamethylenethiuram
• tetrasulfide NEW
• 2,6-Di-tert-butyl-4-ethylphenol
• NEW
• 2,6-Di-tert-butylphenol
• NEW
• Ethanox® 330
• Ethaphos® 368
• Ethanox® 310
• Ethanox® 376
• 2,2'-Ethylidene-bis(4,6-di-tertbutylphenol)
• NEW
• Ethanox® 323
• Ethanox® 702
• 2-(2'-Hydroxy-3',5'-di-tertamylphenyl)
• benzotriazole NEW
• Ethanox® 703
• Irganox® 245
• Irganox® 1035
• Irganox® 1425 WL
• Irganox® 259
• Irganox® 1081
• Irganox® 3125
• Irganox® 565
• Irganox® 1098
• Irganox® 3144 FF
• Irganox® E 201
• Isonox® 232
• Markstat® 60
• Irganox® MD 1024
• Lowinox® AH25
• Naugard® 412S
• Isonox® 132
• Lowinox® CPL
• Naugard® 445
• Lowinox® TBM-6
• Naugard® 635 NEW
• Naugard® 956
• Naugard® HM-22
• Naugard® PHR
• Naugard® A
• Naugard® J
• Naugard® PS-30
• Naugard® B-25
• Naugard® NBC
• Naugard® PS-35
• Naugard® BHT
• Naugard® PANA
• Naugard® Q Extra
• Naugard® RM-51
• Naugard® XL-1
• Bis(2,2,6,6-tetramethyl-4-
• piperidyl) sebacate
• NEW
• Naugard® Super Q
• Propyl gallate NEW
• 2,2'-(2,5-thiophenediyl)
• bis(5-tert-butylbenzoxazole)
• NEW
• Santicizer® 278
• Ultranox® 626
• Antiozonants
• Akrochem® NIBUD
• Akrowax™ 195 NEW
• Blowing Agents/Blowing
• Agents, Plasticizer
• CPW-100
• Celogen® AZ
• Celogen® RA NEW
• Coupling Agents
• Silquest® A-187
• Silquest® A-1102
• Silquest® A-137
• Silquest® A-1100
• Silquest® A-1289
• Silquest® A-2171
• Cross-linking Agents
• F-300, F-1000, F-1500,
• F-2000, F-3000
• Perkacit® MBTS
• Perkacit® ZDEC
• Perkacit® DPG
• Perkacit® NDBC
• Perkacit® MBT
• Resimene® 3520
• Flame Retardants
• Aroclor® 1221
• 2,2',4,4'-Tetrabromodiphenyl
• ether
• 2,2',4,4',6-Pentabromodiphenyl
• ether
• Aroclor® 1232
• 2,2',4,4',5-Pentabromodiphenyl
• ether
• Aroclor® 1016
• Aroclor® 1242
• 2,2',4,4',5,5'-Hexabromodiphenyl
• ether
• Aroclor® 1248
• Aroclor® 1268
• Aroclor® 6050
• Aroclor® 1254
• Aroclor® 5432
• Decabromodiphenyl ether
• Aroclor® 1260
• Aroclor® 5442
• Firemaster BP4A
• Aroclor® 1262
• Aroclor® 5460
• Halowax 1000
• Halowax 1001
• Halowax 1013
• Halowax 1051
• Halowax 1099
• Saytex® 8010 NEW
• m-Terphenyl
• o-Terphenyl
• p-Terphenyl
• Tetradecachloro-mterphenyl
• Tetradecachloro-oterphenyl
• Tetradecachloro-pterphenyl
• Plasticizers
• Benzoflex® 2-45
• Bisphenol A (BPA)
• Celogen® SD-125
• Citroflex 2
• Citroflex 4
• Citroflex A-2
• Citroflex A-4
• Citroflex B-6
• Cresyl diphenyl phosphate
• NEW
• Dibutyl phthalate
• Dibutyl sebacate NEW
• Diisooctyl phthalate NEW
• Dimethyl adipate NEW
• Dimethyl sebacate NEW
• Dioctyl phthalate (DOP)
• Disflamoll® TKP NEW
• Disflamoll TP NEW
• 2-Ethylhexyl sebacate
• NEW
• Bis(2-Ethylhexyl)
• terephthalate NEW
• Hercoflex® 900
• Hi-Point® 90
• Hi-Point PD-1
• Jayflex® 77
• Jayflex® DIDP
• Jayflex® DINP
• Jayflex® DTDP
• Jayflex® L11P-E
• Jayflex® TINTM
• Laurex®
• Markstat® 51
• Methyl O-Acetylricinoleate
• NEW
• Morflex® 150
• Morflex® 190
• Morflex® 560
• Morflex® x-1125
• Paraplex® G-30
• Plasthall® DINP plasticizer
• NEW
• Plasthall® ESO
• Polycizer® butyl oleate
• Polycizer® DP 500
• Santicizer® 141
• Santicizer® 148
• Santicizer® 160
• Santicizer® 261
• Tributylphosphate NEW
• Triethylphosphate NEW
• 2,2,4-Trimethyl-1,3-
• pentanediol-isobutyrate
• NEW
• Trimellitate NEW
• Vinsol® powder
• Vinsol® resin
• Processing aids
• Akrochem® Ceresin
• Wax NEW
• Kemamide® E ultra
• Retarders
• Akrochem® Retarder
• BAX NEW
• 2-Cyano-2-propyl
• benzodithioate NEW
• 4-Cyano-4-(phenylcarbonothioylthio)
• pentanoic acid NEW
• 2-Cyano-2-propyl dodecyl
• trithiocarbonate NEW
• 4-Cyano-4-[(dodecylsulfanylthiocarbonyl)
• sulfanyl]
• pentanoic acid NEW
• Cyanomethyl dodecyl
• trithiocarbonate NEW
• Cyanomethyl methyl(phenyl)
• carbamodithioate
• NEW
• 2-(Dodecylthiocarbonothioylthio)-
• 2-
• methylpropionic acid
• NEW
• Bis(dodecylsulfanylthiocarbonyl)
• disulfide
• NEW
• Retarder AK
• Bis(thiobenzoyl) disulfide
• NEW
• Stearates
• Stearic Acid RG (rubber
• grade)
• Stearic Acid TP
• UV stabilizers
• Tinuvin® PED
• Uvinul® 3000
• Uvinul® 3008
• Uvinul® 3040
• Uvinul® 3049
• Deuterated Compounds
• Dibenzylphthalate-d4
• Di-n-butyl phthalate-d4
• Di-iso-butyl phthalate-
• 3,4,5,6-d4
• Diethyl phthalate-
• 3,4,5,6-d4
• Diethyl phthalate-
• 3,4,5,6-d4
• Di-n-hexyl phthalate-
• 3,4,5,6-d4
• Di-n-hexyl phthalate-
• 3,4,5,6-d4
• Di-n-octyl phthalate-
• 3,4,5,6-d4
• Di-n-pentyl phthalate-
• 3,4,5,6-d4
• Di-n-propyl phthalate-
• 3,4,5,6-d4
• Bis(2-ethylhexyl) phthalate-
• 3,4,5,6-d4

Chapter 2
Antiblock and Slip Agents

• Antiblocking Agents
• Antiblock Agent for
• Polyolefin Films
• Talc antiblock
• compositions and
• method of preparation

Chapter 3
Antioxidants

• Description
• Phenolics
• Organophosphites
• Synthesis of
• Phosphorochloridite
• 1a and Phosphorodichloridite 2a
• Thioesters
• Deactivators
• Recent developments
• Suppliers
• Trends and forecasts

Chapter 4
Antistatic Agents

• Description
• External Antistats
• Dust Test Method
• Trends and forecasts

Chapter 5
Biocides

• Description
• Preparation
• Method
• Suppliers
• Trends and forecasts

Chapter 6
Chemical Blowing Agents

• Description
• Physical blowing agents
• Chemical blowing agents
• Polycarbonic Acid
• Trends and Forecasts

Chapter 7
Coupling Agents

• Description
• Silanes
• trans-2-methylcyclopentylsilane
• Titanates
• Trends and Forecasts

Chapter 8
Flame Retardants

• Description
• Reactive flame retardants
• Brominated Hydrocarbons
• Phosphate esters
• Chlorinated hydrocarbons
• Antimony Oxide
• Aluminum Trihydrate
• Other flame retardants
• Inorganic phosphates
• Melamines
• Magnesium hydroxide
• Molybdenum compounds
• Zinc Borate
• Driving Forces

Chapter 9
Heat Stabilizers

• Description
• Primary heat stabilizers
• Mixed metal stabilizers
• Lead Heat Stabilizers
• Secondary heat stabilizers
• Alkyl/aryl organophosphites
• Epoxy Compounds
• Beta diketones
• Polyfunctional Alcohols
• Trends and Forecasts

Chapter 10
Impact Modifiers

• Description
• Methacrylate-butadiene-styrene (MBS)
• Acrylonitrile-butadienestyrene (ABS)
• Acrylics
• Acrylic Sheet Production
• Chlorinated polyethylene (CPE)
• Ethylene vinyl acetate (EVA)
• Ethylene propylene diene monomer (EPDM)
• Maleic anhydride grafted EPDM

Chapter 11
Light Stabilizers

• Description
• Benzophenone
• Preparation
• Benzotriazole
• Benzoates and Salicylates
• Nickel Organic Complexes
• Hindered Amine Light
• Stabilizers (HALS)
• Suppliers
• Trends and Forecasts

Chapter 12
Lubricants and Mould Release Agents

• Description
• Lubricants
• Metallic stearates Esters
• Fatty Amides
• Synthetic Protocols
• Cis-9,10-octadecenoamide
• Trans-9,10-octadecenoamide
• Cis-8,9-octadecenoamide
• Cis-11,12-octadecenoamide
• Oleic acid
• Erucamide
• Methyl-8-hydroxyoctanoate
• Methyl-8-bromooctanoate
• Methyl-8-triphenylphosphoranyloctanoatebromide
• Methyl-cis-8.9-octadecenoate
• Cis-8,9 octadecenoic Acid
• 18-Hemisuccinate-cis-9,
• 10-octadecenoamide
• Methyl-9-bromononanoate
• Methyl-9-triphenylphosphoranylnonanoate-bromide
• Methyl-18-t-butyldiphenysilyloxy-cis-9,10 octadecenoate
• 18-T-butyldiphenylsilyloxycis-
• 9,10-octadecenoic Acid
• 18-T-butyldiphenylsilyloxycis-
• 9,10-octadecenoamide
• 18-Hydroxy-cis-9,10-octadecenoamide
• Synthesis of
• Compound 100
• Methyl-9-bromo-nonanoate
• (Intermediate for Compound 100:)
• 9-T-butyldiphenylsilyloxynonanal
• (Intermediate for Compound 100:)
• Methyl-9-triphenylphosphoranylnonanoate
• Bromide
• (Intermediate for Compound 100:)
• Methyl-18-t-butyldiphenysilyloxy-
• cis-9,10-
• octadecenoate
• (Intermediate for Compound 100:)
• 18-T-butyldiphenylsilyloxy-cis-
• 9,10-octadecenoic Acid (Compound 100:)
• Fatty Alcohols
• Waxes
• Mould Release Agents
• Fatty Acid Esters and Amides
• Fluoropolymers
• Silicones
• Suppliers
• Trends and forecasts

Chapter 13
Nucleating Agents

• Description
• Types
• Substituted sorbitols
• Low Molecular Weight Polyolefins
• Sodium benzoate
• Ionomer Resins
• Suppliers
• Trends and forecasts