EPOXIDIZED SOYABEAN OIL (SECONDARY PLASTICIZER) USED IN PVC COMPOUND (CAP: 5 MT/DAY)
[EIRI/EDPR/4535] J.C.: 2752XL
Epoxidized soybean Oil (ESBO) is an additive to flexible Polyvinyl Chloride (PVC) that gains its name from the reaction that occurs with the unsaturated soybean oil. The epoxidation reaction takes place at a carbon to carbon double bond site. The oxygen atom (usually in the form of peroxide or a peracid) comes in and attaches itself between the two carbons to create a single bonded triangular ring between the three molecules called an oxirane. This oxirane can be used as a way of separate well formed ESO molecules from those that will be less effective. Those ESO molecules with higher oxirane percentages will product better results than those with low oxirane percentages.
Because epoxidized soybean oil is synthesized from the bio-based, renewable resource of soybean crops, the level of saturation of the soybean oil and ultimately the oxirane value of the ESO created from it, is dependent on the growing conditions of the soybeans. Very hot, dry weather is known to inhibit the formation of the unsaturated C18-3 and C18-2 double bonds in the soybean oil and will therefore lead to lower oxirane values in the ESO produced from it.
The climate of American Midwest is very well suited to producing high oxirane value ESO. The United States is responsible for about 32% of the total soybeans grown worldwide, with Brazil and Argentina also significant producers of the oilseed.
Although ESO was first introduced into the plastics market over thirty years ago as a bio based plasticizer that could be a drop-in replacement to Dioctyl phthalate (DOP), it has found a strong niche as a secondary plasticizer due to its heat and light stabilization effects in PVC compounds. The epoxide group is more reactive than a double bond, thus providing a more energetically favorable site for reaction and making it a good hydrochloric acid scavenger and plasticizer.
Epoxidized soybean oil, better known by its acronym, ESBO, is a plasticizer used in polyvinyl chloride (PVC) plastics. It serves as a plasticizer and as a scavenger for hydrochloric acid liberated from PVC when the PVC undergoes heat treatment
COST ESTIMATION
Plant Capacity 5 MT/Day
Land & Building (4000 sq.mt.) Rs. 1.92 Cr
Plant & Machinery Rs. 2.66 Cr
Working Capital for 1 Month Rs. 1.31 Cr
Total Capital Investment Rs. 6.23 Cr
Rate of Return 31%
Break Even Point 55%
CONTENTS
INTRODUCTION
EPOXIDIZED LINOLEIN A MAJOR COMPONENT OF ESBO
CHARACTERISTICS OF EPOXIDIZED SOYABEAN OIL
TYPICAL PROPERTIES OF EPOXIDIZED SOYBEAN OIL
HEAT STABILITY
GOOD IN NON-MIGRATION
WATER RESISTANCE
LOW VOLATILITY
STORAGE, SAFETY, PACKING
STORAGE AND TRANSPORTATION
SAFETY
SPECIFICATION OF EPOXIDIZED SOYABEAN OIL
SPECIFICATIONS
NATURE OF ESBO
PROCESSING ADVANTAGES:
1. NEUTRALIZATION OF HCL
2. SUBSTITUTION OF LABILE CHLORINE
LUBRICATION ASPECTS:
AS A PLASTICIZER:
PREVENT ANTIPLASTICIZATION:
CONTRIBUTION OF EPOXIDIZED SOYABEAN OIL IN PVC PROCESSING
ESBO ACTS IN MULTIPLE WAYS:
USES AND APPLICATION
APPLICATIONS
TOXICITY OF EPOXIDIZED SOYABEAN OIL
FOOD SAFETY AND LEGISLATION FOR EPOXIDIZED SOYABEAN OIL
LEGISLATION
B.I.S. SPECIFICATION
GRADE OF EPOXIDIZED SOYA BEAN OIL
COMPATIBILITY AND DOSAGE OF ESBO
APPLICATIONS
COMPATIBILITY
RECOMMENDED DOSAGE
PLASTICIZED PVC
RIGID PVC
MARKET POTENTIAL OF BIO PLASTICIZER
COMPETITIVE DYNAMICS:
BY TYPE
BY APPLICATION:
REGIONAL ANALYSIS:
MARKET OVERVIEW OF EPOXIDIZED SOYBEAN OIL
GLOBAL EPOXIDIZED SOYBEAN OIL MARKET OVERVIEW
GLOBAL EPOXIDIZED SOYBEAN OIL MARKET: SEGMENTATION ANALYSIS
EPOXIDIZED SOYBEAN OIL MARKET BY RAW MATERIAL
EPOXIDIZED SOYBEAN OIL MARKET BY APPLICATION
EPOXIDIZED SOYBEAN OIL MARKET BY END-USER
EPOXIDIZED SOYBEAN OIL MARKET BY GEOGRAPHY
KEY PLAYERS IN EPOXIDIZED SOYBEAN OIL MARKET
THE MAJOR PLAYERS IN THE MARKET ARE AS FOLLOWS:
MARKET SCENARIO OF PLASTICIZER
FIGURE: MARKET SHARE OF PLASTICIZERS IN VARIOUS APPLICATIONS
GLOBAL MARKET TRENDS OF PLASTICIZER
GLOBAL PROMINENT PLAYERS
TABLE: GLOBAL PLAYERS OF PLASTICIZERS
INDIAN MARKET TRENDS
INDIAN INSTALLED CAPACITY
TABLE: INSTALLED CAPACITY OF PLASTICIZER IN INDIA
OUTLOOK
PRESENT MANUFACTURES AND SUPPLIERS OF EPOXIDIZED SOYABEAN OIL
FORMULATION OF EPOXIDIZED SOYABEAN OIL
MANUFACUTRING PROCESS OF EPOXIDIZED SOYABEAN OIL (SECONDARY PLASTICIZER) USED IN PVC COMPOUND
EPOXIDATION OF SOYBEAN OIL TO OBTAIN EPOXIDIZED SOYABEAN OIL (ESBO)
PROCESS DESCRIPTION FOR EPOXIDATION OF SOYABEAN OIL
SAFETY CRITERIA FOR THE EPOXIDATION OF SOYABEAN OIL
SAFETY CRITERIA
REACTION SCHEME OF EPOXIDATION PROCESS
REACTION SCHEME
SCHEME OF THE EPOXIDATION REACTIONS
MASS AND ENERGY EQUATIONS
PROCESS FLOW DIAGRAM OF EPOXIDIZED SOYABEAN OIL (SECONDARY PLASTICIZER) USED IN PVC COMPOUND
MANUFACTURING PROCESS AND MASS BALANCE OF EPOXY PLASTICIZER
CHEMICAL REACTION OF EPOXIDIZED SOYBEAN OIL
MASS BALANCE OF EPOXY PLASTICIZER
TESTING PROCEDUSE FOR EPOXIDIZED SOYABEAN OIL
ANALYTICAL METHODS
TITRATION OF EPOXY (OXIRANE OXYGEN)
FTIR SPECTRUM
EPOXY CONTENTS OF ESO
FTIR OF TRIGLYCERIDES AND EPOXIDIZED TRIGLYCERIDES
DIFFERENT METHOD OF EPOXIDATION
ESTABLISHED METHODS OF EPOXIDATION ARE AS FOLLOWS:
CONVENTIONAL CHEMICAL TREATMENT
II) ACID ION EXCHANGE RESIN (AIER) METHOD
III) ENZYMATIC METHOD
IV) METAL CATALYST METHOD
PROCESS INTENSIFICATION AND KINETICS FOR EPOXIDATION OF SOYABEAN OIL
TABLE 1: KINETIC EXPRESSION, KINETIC LAWS AND ACTIVATION ENERGY
REACTION MECHANISM AND KINETICS OF EPOXIDATION
REACTION MECHANISM
KINETICS OF EPOXIDATION
STEP I: FORMATION OF PEROXYACETIC ACID
STEP II: EPOXIDATION RECTION
THERMODYNAMIC PROPERTIES OF THE EPOXIDIZED VEGETABLE OIL
CONTINUOUS EPOXIDATION FLOW PROCESS
CONTINUOUS FLOW STIRRED TANK CASCADE
VEGETABLE OIL
PHASE-TRANSFER CATALYSED EPOXIDATION OF SOYABEAN OIL USING HYDROGEN PEROXIDE AND SUPERCRITICAL CARBON DIOXIDE
MATERIAL SAFETY DATA SHEET
CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
HAZARD(S) IDENTIFICATION
COMPOSITION / INFORMATION ON INGREDIENTS
FIRST AID MEASURES
FIRE-FIGHTING MEASURES
ACCIDENTAL RELEASE MEASURES
HANDLING AND STORAGE:
EXPOSURE CONTROLS / PERSONAL PROTECTION
PHYSICAL AND CHEMICAL PROPERTIES
STABILITY AND REACTIVITY
TOXICOLOGICAL INFORMATION
SUPPLIERS OF RAW MATERIALS
SUPPLIERS OF ACETIC ACID
SUPPLIERS OF HYDROGEN PEROXIDE
SUPPLIERS OF SULPHURIC ACID
COMPLETE PLANT AND MACHINERY SUPPLIERS
SUPPLIERS OF PLANT AND MACHINERIES
SUPPLIERS OF BOILERS
SUPPLIERS OF REACTORS
SUPPLIERS OF OIL STORAGE TANK
SUPPLIERS OF OIL PACKAGING MACHINE
SUPPLIERS OF FILTER PRESS
APPENDIX – A:
01. PLANT ECONOMICS
02. LAND & BUILDING
03. PLANT AND MACHINERY
04. OTHER FIXED ASSESTS
05. FIXED CAPITAL
06. RAW MATERIAL
07. SALARY AND WAGES
08. UTILITIES AND OVERHEADS
09. TOTAL WORKING CAPITAL
10. TOTAL CAPITAL INVESTMENT
11. COST OF PRODUCTION
12. TURN OVER/ANNUM
13. BREAK EVEN POINT
14. RESOURCES FOR FINANCE
15. INSTALMENT PAYABLE IN 5 YEARS
16. DEPRECIATION CHART FOR 5 YEARS
17. PROFIT ANALYSIS FOR 5 YEARS
18. PROJECTED BALANCE SHEET FOR (5 YEARS)
